Staff - Fairfield County's Community Foundation. Executive Office. Juanita T. James, President & CEOJuanita T. James joined the Community Foundation in 2. She previously served as chief marketing and communications officer for Pitney Bowes Inc. Prior to Pitney Bowes, she held key roles at Time Warner, Inc. Her long history of leadership and volunteer service with local and national nonprofits has been recognized with numerous awards, including the NAACP . ![]() ![]() At the Stamford campus. About CCDA Who is CCDA? The Community Development Block Grant (CDBG) program was established by the Housing and Community Development Act of 1974. Stamford Community Development Stamford, CT Send email. ![]() The City of Stamford makes available its annual allocation of funding from the United States Department of Housing and Urban Development (HUD) under their HOME Investment Partnerships Program. Owner occupants may apply for. EXCHANGE: Redevelopment program improves blighted homes. Published 1:05 am, Saturday, September 17, 2016. Apply to 737 Program Development jobs in Stamford, CT on LinkedIn. Sign-up today, leverage your professional network, and get hired. New Program Development jobs added daily. She lives in Stamford with her husband. They have one son. Contact Juanita: fandre@fccfoundation. Karen R. Brown, Vice President. She is responsible for keeping us abreast of trends and best practices in the community foundation sector, and promoting learning, innovation and thought leadership. She is a board member of Social Venture Partners Connecticut, the Support Center for Nonprofit Management, and serves on the program committee for the Connecticut Council for Philanthropy, the steering committee for the Fairfield County Collaborative Fund for Affordable Housing, and the Connecticut committee of the Regional Plan Association. Karen graduated Phi Beta Kappa from Brown University, and holds a master. Wagner Graduate School of Public Service at New York University. She co- founded the Wagner Alumni in Philanthropy Network. She received the Connecticut Council for Philanthropy. Newman Award for sustained and exemplary staff performance at a Connecticut foundation. ![]() Contact Karen: KBrown@FCCFoundation. Program. Nancy M. She served as Program Director, overseeing the grant making and community leadership for the Economic Opportunity and Health and Human Services priority areas before being named Vice President of Programs in February 2. Nancy also serves as the staff liaison to the Bridgeport Public Housing Resident Support Fund at the Community Foundation, a donor- advised fund set up to benefit residents of Bridgeport public housing; and manages the PT Partners initiative, a collaborative, resident- driven initiative aimed at developing and demonstrating a sustainable and replicable process for community transformation within public housing neighborhoods. Nancy brings more than 2. Nancy graduated with honors from Vassar College, where she earned a B. A. She also holds a Master. Wagner Graduate School of Public Service at New York University, where she was a Dean. She serves on the board of the Southern Connecticut Chapter of the American Foundation for Suicide Prevention. Contact Nancy: Nvon. Euler@FCCFoundation. Alexis Bivens, Director of Thrive by 2. Alexis joined the Community Foundation in 2. She is director of Thrive by 2. Fairfield County. In her role, she will be responsible for developing and leading this critical initiative in partnership with community partners and Community Foundation teams. Alexis received her bachelor. Her previous work experience includes teaching under- credited high school students, facilitating trainings and workshops on youth development strategies, as well as program assessment. Alexis lives in Hamden with her family. Contact Alexis. She also teaches social welfare policy and social work practice at Sacred Heart University, where she is an honorary member of Phi Alpha, the national social work honor society at the university. Kate previously served as director of resident services at the Housing Authority of the City of Bridgeport, and as a trauma and homeless services specialist at the Department of Veterans Affairs campus in West Haven. She co- chairs Greater Bridgeport Opening Doors, and authored the Bridgeport Housing First framework, which has housed nearly 2. Kate is a graduate of Yale University and the University of Connecticut School of Social Work, and continued her social work education as a clinician and fellow of both the Yale University Supportive Housing Program and the Yale- VA Psychosocial Rehabilitation Program. She lives in New Haven with Dave and their dogs. Contact Kate: KKelly@FCCFoundation. Carol Guernsey, Arts & Culture Fund. Carol has held positions in Corporate and Foundation Relations, Development and Events Planning at World Monuments Fund, The Metropolitan Museum of Art, Guggenheim Museum, The Museum of Modern Art and Americans for the Arts. Additionally, Carol has also done extensive arts related volunteer work in local schools. Carol holds a BS in Art from James Madison University and a MA in Visual Arts Administration from New York University. Contact Carol: CGuernsey@FCCFoundation. January Romero Reissman, Program Associate, Education & Youth Development. January joined the Community Foundation in 2. She is responsible for grantmaking and community leadership in the areas of education and youth development. January previously served as an associate at Achievement First, a nonprofit charter management organization. She brings a variety of experiences from organizations such as NYU, U. S. Fund for UNICEF, Lawyers Alliance for New York and Cooperaci. She was captain of the Yale women. She previously served as Nursing Scheduler for Family Care Visiting Nurse Agency, and Office Manager for Bindi Desserts, Inc. As an administrative assistant, Sharon provides administrative support to the program staff. She lives in Norwalk with her son, Cameron, and her daughter, Jade. Contact Sharon: SJones@FCCFoundation. Center for Nonprofit Excellence. Elaine V. Elaine serves as a key liaison to the Fairfield County nonprofit community and is dedicated to strengthening the region. Elaine is responsible for leading the Community Foundation’s. Prior to joining the Foundation, she served as the director of the Greater Danbury Nonprofit Resource Center providing training, consulting and volunteers for nonprofit organizations in northern Fairfield County. She led the Greater Danbury Nonprofit Resource Center from its inception in 2. Community Foundation in 2. Prior to her nonprofit work, Elaine served at the state level as a research consultant with the Office of Policy & Management and as a staff member to the Appropriations Committee with the CT General Assembly. She also served as an adjunct faculty member in the Political Science Department at Norwalk Com. Previously, he traveled the country for over 2. Ameri. Corps, fighting off blackberry vines, constructing Habitat for Humanity homes and tilling the roots for a youth- led community garden. He worked with the Northeast Organic Farming Association of Connecticut, and most recently served as the Bridgeport Program Manager with Public Allies Connecticut. There he coached, trained and empowered emerging, diverse leaders in the nonprofit sector, and was recognized in 2. His hometown is Stamford, where he now lives. Contact RJ: RMercede@FCCFoundation. The Fund for Women and Girls. Tricia A. Hyacinth, Manager. Tricia joined the Community Foundation in 2. She previously served as program manager for community engagement at a nonprofit in Hartford, an academic administrator and instructor, and a corporate marketing consultant. Tricia offers extensive experience working with volunteers, and organizing and executing large- scale service events. She holds an MBA in marketing/management from the University of Connecticut and degrees in political science. She enjoys traveling and lives in Monroe with her family. Contact Tricia: THyacinth@FCCFoundation. Alex Quesada, Administrative Assistant. Alex joined the Community Foundation in 2. She provides administrative support for the Fund for Women and Girls and helps coordinate events. She previously served as an associate for the American Cancer Society, Inc. Alex holds a bachelor’s degree from the University of Connecticut, and an associate degree from Norwalk Community College. She lives in Norwalk with her family. Contact Alex: AQuesada@FCCFoundation. Donor Services & Development. Fiona K. Hodgson, Vice President of Development and Philanthropic Services. Fiona joined Fairfield County’s Community Foundation in 2. Fiona lived in Boston for many years, working at Brandeis University, Boston College and Harvard Medical School, where she ran a large capital campaign. She returned to her native England to run the inaugural global campaign for her alma mater, the London School of Economics. Back in the US, Fiona joined Save the Children, where she led a successful $4. She is a board director for the Association of Fundraising Professionals and for the Interfaith Council, and is on the vestry of Christ and Holy Trinity Church, Westport. Contact Fiona: FHodgson@FCCFoundation. Kristy Jelenik, Development. She previously served as director of development for Family Centered Services of Connecticut and has more than 1. NY and CT. She works with Foundation donors and fundholders to grow their charitable giving and introduce them to new opportunities to make an impact with their philanthropy. Kristy holds a Bachelor. She is an active volunteer in Fairfield where she lives with her two children and husband. Contact Kristy: KJelenik@FCCFoundation. Carole S. Schwartz, Corporate and Foundation Relations Manager. Carole joined the Community Foundation in 2. She previously served as director of corporate and foundation relations at Inspirica (formerly St. Previously, she served as a planned giving officer in the development department of Fairfield University following an extensive career in banking, focusing on financial planning and wealth management. Nancy was a VP and trust officer at BNY Mellon, formerly Putnam Trust, where she developed relationships in the Greenwich, Southport and Westport communities. Throughout her executive career, Nancy remained involved with community causes including Greenwich Special Olympics where she served as local coordinator. She was a leader in Putnam Trust. She acquired a certified Financial Services Counsellor accreditation from the American Bankers Association National Graduate Trust School. Nancy lives in Fairfield with her husband, Ronald Lowe, and they are avid golfers and active volunteers at St.
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Best Prezi Presentation Alternatives by Pow. Toon! In the last couple of years many people have been searching for innovative ways to create executive, unique, and memorable presentations. Power. Point was exciting in the early days of its launch, but too many boring presentations led to the creation of new softwares like Prezi. Prezi presentations helped to prevent us from falling asleep during presentations, but the zooming in and out effects of their software, and limited manipulation capabilities, called for more options and new players in the presentation market. Pow. Toon – Best Prezi Alternative. Of course our very own Pow. Toon made the top of our Prezi presentation alternatives list! We love our suite of animated characters, library styles, awesome templates, and special effects. The best part about Pow. Toon is that the finished product will look professionally designed, and so creative, that your audience will think you hired a professional to create it. To show you what we’re all about, take a look at a Pow. PowerPoint was excitin. RawShorts – Prezi Alternative. The most prominent example of presentation software is Microsoft PowerPoint. Other examples include. Emaze is the next generation of online presentation technology, enabling beautiful presentation design automatically. With more than 20M presentations created on the. Explore how PowerPoint can help you tell a powerful story in your presentations and. Toon created by one of our users. Our simple, fun interface requires you to simply drag and drop elements and characters, and the rest is pure magic! Pow. Toon is perfect for educators, students, small business owners, and entrepreneurs. It is even great for designers who wish to flex their creative side without having to fuss with designs from scratch. Pow. Toon #Slides – Best Slideshow Prezi Alternative. Pow. 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Images can be easily accessed from your own photo albums, the supplied stock photos, or through a quick internet search. This software does all the work so you don’t have to stress, but the app is limited to i. Pad users, and has less features than some of our other favorites. Raw. Shorts – Prezi Alternative. Raw. Shorts is a winner in the video presentation category. With an instinctive interface that doesn’t seem to require heavy tutorials, you can create any kind of video that you desire. These kinds of videos are important for websites, blogs, You. Tube channels, and all other kinds of demos. However, Raw. Short falls a bit short on the presentation side of things. You are not really able to integrate slides with your video. Sparkol Video. Scribe – The Scribing Prezi Alternative. We included this great software in our top five PRezi presentation alternatives because it is very unique. Video. Scribe software sketches the desired characters for the viewers, which makes any story come to life. This style of video hooks the audience and creates intrigue. This is not geared for live presentations, but certainly works well for online video presentations. Our Bonus Prezi Presentation Alternative. Slid. es“Slid. es”, as their name suggest, really explains what the company offers. It is great for slideshow presentations. It is perfect for quick and easy professional looking presentations that don’t require animation or too many effects. Since there aren’t any templates to choose from , you only have to rely on great visuals. The good news is that Slid. HTML5 based, and integrates movable gifs to give the illusion that there is video integrated into the presentation. This is also a great Prezi presentation alternative that you should definitely check out! Five Best Power. Point Alternatives When you need to create an interesting and engaging presentation for your boss, new clients, or a job interview, you have plenty of options for tools to get the job done. Plus, even though it's the industry standard, you don't have to your Microsoft Power. Point, and many people would argue there are better tools for the job anyway. This week we're going to look at five of the best of those alternative presentation tools, based on your nominations. Earlier in the week, we asked you which applications you preferred to use to make slideshows and presentations when Power. Point wasn't an option. You definitely responded, some of you passionately noting that your favorite was better than Power. Point anyway. We can't highlight all of the nominees, but here are the top five. Creating dazzling presentations for clients, business meetings, or even job interviews doesn't . To see which Power. Point alternative you think is the best, head over to our weekly hive five followup post to check out the winner! Creating an interesting, informative, and elegant presentation or slideshow for a company meeting. Many of you thought the same, and pointed out that it's very easy to create good- looking presentations with Keynote without spending time digging through menus or looking for templates that haven't been used to death by everyone else. Keynote has great built- in graphic tools to edit and tweak the images going into your presentations, easily supports videos and movies on your slides or as part of your presentation, has non- hokey- looking animations, supports Power. Point documents if you need to spice up someone else's presentation, and even lets you control your presentation from your i. OS device or project the presentation via video out and look at your notes and the upcoming slides on your Mac's display. Google Docs' presentations module used to be fairly lackluster, but they've updated it recently to make it more compatible with people coming over from Microsoft Office, or people who want a more robust presentations tool. Google Docs offers a wealth of templates and presentation creation tools that are easy to jump in and get started with, animations and slide transitions to make your presentation interesting to watch, and even collaborative presentation editing with other people on your team. You may miss some heavier features like video embedding in your slides (although you can embed You. Tube or other web video), if you don't need the bells and whistles of a pricier app and just want a fast, free way to create good- looking slideshows on any system, this is it. Google Docs has rolled out a new version of its presentations tool with over 5. Where other presentation tools give you a GUI where you drag in elements you want to use like images and video and then tweak text boxes to include the information you want on screen, Beamer requires you to build your presentation in a custom markup language that works for just about any La. Te. X document. If you're looking for fast and easy- to- use, this isn't it, but if you're already familiar with La. Te. X and have used it in the past (it's extremely popular in academia and by technical folks who would rather write their own presentations and tweak every possible feature than give up control to a GUI), then it offers a level of granular control that other tools don't provide. Prezi (Web/Win/Mac/Linux/i. OS: Free, $5. 9/yr . Even the animations and transitions available in other slideshow applications pale in comparison to Prezi's . To some it's all too overwhelming and distracting from the core message of the presentation, and some have called Prezi's flashy presentation templates unprofessional, but many more have noted that Prezi's tools make it easy to create presentations that are truly interesting and a world apart from the dull slideshows we're all used to. You can create an account for free and start building presentations on the web, up to a 1. MB storage limit. When Libre. Office split off as a fork of Open. Office. org, it took Impress with it, and now both platforms use essentially the same tool for slideshows and presentations. Both version support Power. Point presentations, and offer an easy- to- use drag- and- drop UI for building new presentations that you'll be familiar with if you've used any of the other tools listed here. In fact, Impress most closely matches Power. Point in terms of UI and layout of any of the tools here, but extends its draewing and graphics capabilities a bit. Now that you've seen the top five, it's time to put them all to a vote and decide the winner. Honorable mentions this week go out to Sliderocket, which came in with just a few nominations shy to make the top five, and the previously mentioneddeck. Traditionally, creating presentations requires using an app like Powerpoint and can cause various? Have something to say about one of the contenders that we missed? Remember, the Hive Five contenders are based on your nominations in the call for contenders thread from earlier in the week. Let's hear it in the comments below. Title image remixed from Losevsky Pavel (Shutterstock). Aud- X 5. 1 Surround Codec Download. Simple- to- use software application that helps you encode AC3 and WAV files, and decode MP3s which can be turned to AC3 tracks with different bitrate values. Sound quality is paramount for anyone who enjoys listening to music and watching movies onto their home computer. For this reason, having the appropriate tools for decoding audio streams and encoding the sound to obtain the best output possible is a must. Aud- X 5. 1 Surround Codec is one such utility, easy to install and not at all difficult to set up, even by less experienced users. This video is to check your Sourround System (YouTube only supports 2 Channel Stereo Sound - but the sound is amazing) Try also the THX Surround Sound Video.This particular codec has a configuration area that will make it possible for you to adjust the encoding and decoding settings in a quite simple manner. Encoding settings. The quality for audio encoding starts from 8. Aud- X 5. 1 Surround Codec supports AC3 and WAV file formats for this operation and you can easily choose the track to process by pressing the 'Encode file' button. Decoding options. Insofar as decoding sound files is concerned, the software application can handle MP3s which can be turned into AC3 tracks with bitrates from 1. Also, Aud- X 5. 1 Surround Codec is able to decode tracks into PCM format, namely 6 channel uncompressed audio files. Extra configuration settings. There are even more configurations you can tinker with and they are related to the Aud- X Direct. Show filter. Thus, by checking the corresponding box, you will be able to set this codec as the default one for decoding AC3, PCM, MP3 as well as all Aud- X streams. In case you have other decoders installed onto your system and still want Aud- X 5. Surround Codec to handle one of the above mentioned formats, the filter will become the last chain in the processing of the streams. Bottom line. All things considered, when it comes to transforming regular movie soundtracks or music files into amazing surround audio, this particular software program may prove to be just what you need. Download Winamp We are working hard to reenergize Winamp! Follow this link to get updated news. Shoutcast Internet Radio. Stations: Now playing: Listeners: idobi Radio: New. Simple Audacity tutorial on how to upmix a stereo audio recording to surround sound. This covers mixing any stereo file (song, recording), into a 6 channel file for 5.1 surround. The main use for this is if you have. 5.1 Surround Sound Not Working. Winamp Technical Support The free customizable Winamp media player that plays mp3 + other audio files, syncs your iPod, subscribes to Podcasts and more. This program received 1 award. Download Winamp 7.1 Surround Sound - real advice. Dolby for Winamp and 2 more programs. ![]() Easy- to- customize and with a decent feature set, Aud- X 5. Surround Codec is a really good choice and is suitable for all users, regardless of their experience in sound processing.
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Ambassador & Affiliate program; Our Brand Book; PSA Coupons. Perfect Supplements manfactures the highest quality health supplements, we use NO FILLERS or FLOWING AGENTS in any of our products. 5/7/2017 0 Comments User Program To Memory CardYou can use this slot to transfer data among digital cameras, camcorders, music players, and other audio/video devices. The SD memory card slot on the computer can accommodate the following memory cards: To insert an SD memory card Locate the SD memory card slot. Hold the SD memory card with the arrow pointing toward the slot, and carefully slide it into the slot until it clicks into place. Number of pictures that can be stored on a memory device: 5: SanDisk SSD Dashboard Support. Warranty and User Guides. The date of purchase by the original end user customer. Flash Memory Guide 4 Card Readers. CardRecovery User Testimonials . ![]() The SD memory card icon will appear in the Computer window after you insert the card into the slot. Note Be careful not to insert an SD memory card with wrong orientation. If you force it into the slot upside down, the slot may be damaged. Refer to the manual that came with the SD memory card for more information. The SD memory card icon will not appear in the Computer window until you insert the card into the slot. Hint When you insert the SD memory card into the slot for the first time, you may be prompted to install driver software. If prompted, follow the on- screen instructions to install the software. While data is being read from or written to the SD memory card, the media access indicator light is on. To remove an SD memory card Locate the SD memory card slot. Card Readers; SSD (Solid State Drives). FAQs and information on how to contact Technical Support. KODAK SD MultiMedia Card Reader-Writer Software - WINDOWS Operating. COMPACTFLASH Memory Cards for use. Reader-Writer Software - WINDOWS Operating Systems. SanDisk Extreme CompactFlash Memory Card; SanDisk Ultra CompactFlash Memory Card; CFast 2.0 Cards. SanDisk Extreme PRO CFast 2.0 Memory Card; Memory Card Readers. Check that the media access indicator light is off. Push in the SD memory card toward your VAIO computer and release. Pull the SD memory card out of the slot. Nitroglycerin (Transdermal Route) Description and Brand Names. Drug information provided by: Micromedex. US Brand Name. Minitran. Nitrek. Nitro- Bid. Nitro- Dur. Canadian Brand Name. Nitrodur 0. 2Nitro- Dur 0. Nitro- Dur 0. 3Nitrodur 0. Nitro- Dur 0. 4Nitrodur 0. Nitro- Dur 0. 6Nitro- Dur 0. Transderm- Nitro. Trinipatch 0. 2Trinipatch 0. Trinipatch 0. 6Descriptions. Nitroglycerin ointment or skin patch is used to prevent angina (chest pain) caused by coronary artery disease. It does not work fast enough to relieve the pain of an angina attack that has already started. Nitroglycerin belongs to the group of medicines called nitrates. It works by relaxing the blood vessels and increasing the supply of blood and oxygen to the heart while reducing its work load. When used regularly on a long- term basis, this helps prevent angina attacks from occurring. What should I discuss with my healthcare provider before using nitroglycerin transdermal (Minitran, Nitrek, Nitro TD Patch-A, Nitro-Dur)? How should I use nitroglycerin transdermal (Minitran, Nitrek, Nitro TD Patch-A, Nitro-Dur)? NITRO-DUR (Nitroglycerin Transdermal System) Page 1 of 27 PRODUCT MONOGRAPH INCLUDING PATIENT MEDICATION INFORMATION NITRO-DUR ![]() ![]() ![]() And whose molecular weight is 227.09. The organic nitrates are vasodilators, active on both arteries and veins. If the patch falls off The NITRO-DUR transdermal system contains nitroglycerin in acrylic-based polymer adhesives with a. A cardioverter/defibrillator should not be discharged through a paddle electrode that overlies a NITRO-DUR patch. The arcing that may be seen in this. This medicine is available only with your doctor's prescription. This product is available in the following dosage forms: Ointment. ![]() Patch, Extended Release. Portions of this document last updated: April 0. Copyright . Information is for End User's use only and may not be sold, redistributed or otherwise used for commercial purposes. ![]() Graphics corruption in Fallout 4 since 1. I have an Iris 5. Intel GPUs, regardless of hardware. More images are in this gallery here. Basically, the textures stretch and warp, almost always obscuring your view and looking like a mess. It's interesting to note that this does not happen to player/character models, although it's difficult to discern what these textures originally were to begin with. Updating to the latest beta driver does not fix it (although I'd never seen the bright red texture glitch in the gallery before it, so.. In fact, there seems to be something about the 1. AMD. Someone will probably inevitably say that Apple has requested that all issues with their products should be directed through their support, but quite frankly, this doesn't seem like an Apple problem (and the Apple person I talked to agreed with me, saying they can only work to apply fixes within OS X). The game was made by Bethesda, runs solely in a Windows environment, and the common denominator seems to be the Intel GPU. Bethesda is aware of the problem, but are under no obligation to support users of hardware they never offered support to. While I don't know much about driver programming, I feel like this is an issue that will most likely be solved by you at Intel if it is solved at all. You also are under no obligation to solve the problem, and if you can't, no hard feelings (really). This GPU has felt like . The game runs just fine on versions 1. I'm continuing to play the game thanks to downgrade patches, but any future content will be unavailable unless the issue is fixed. I've attached the Intel SSU diagnostics, Dx. Diag, and Disp. Diag for reference, but a summary of my system specs is as follows: Macbook Pro Retina, Late- 2. 23,866 pages on this wiki. Patch 1.6: 1.6.3 July 5, 2016 July 18, 2016 July 18, 2016 release notes: Patch 1.5: 1.5.157. Bethesda's issued a new Fallout 4 patch for the PS4 version of the 1.4 patch. This new patch isn't the upcoming 1.5 update. Instead, it's a 1.05 update that prepares the PlayStation 4 and its version of Fallout 4. Intel Core i. 5- 4. U CPU @ 2. 4. 0GHz, Intel Iris Graphics 5. GB RAM, Windows 1. Pro, graphics driver version 2. ![]() ![]() I think is the beta driver? I was previously on the last stable release, which I found to run significantly better than the Apple- provided one that installs during Boot Camp. ![]() ![]() Sorry for the info dump, I'm just really interested in helping to figure out a solution if possible. I know this has been posted about a few times as well, hope this isn't a problem as I didn't want to hijack any more threads. If there's anything else I can do to help, please let me know - - I'm hoping I'll be able to get some users not on Apple hardware to post their information as well. Thank you in advance! Official site of Fallout 4, the latest edition in the Bethesda series. Description: Fallout v1.0 - v1.1. 3 - Fallout v1.1 Patch (Win95 version) 4 - Fallout v1.0 - v1.1 Patch. You can start using our download services to download Fallout v1.0 - v1.1 Patch by creating a free account on. Fallout 4 Patch 1.7.9 - 1.6.9 Downgrade -. 0 Nuclear option bug 12. Official Fallout 3 Patch 1.4.0.6 para Fallout 3. Categoria: Patches Oficiais Nome do. ![]() Fallout 4's 1.5 update is public for all users on Steam. 0 Replies Latest reply on Apr 28., patch. Download Fallout 3 - v1.0.0.15 Patch. Update 1.0.0.15 Notes. 4 - Fallout 3 - Patch v1.7.0 (German) 5 - Fallout 3 - Patch v1.7. Fallout 3 patch 1.4 was released on March 2. It updates Fallout 3 to version 1.4.0.6. 5/7/2017 0 Comments Properties Of Real Gases PdfReal Gases - Chemistry Libre. Texts. Gases that deviate from ideality are known as Real Gases, which originate from two factors: (1) First, the theory assumes that as pressure increases, the volume of a gas becomes very small and approaches zero. While it does approach a small number, it will not be zero because molecules do occupy space (i. ![]() These become increasingly important in low temperatures, when translational (definition of translational, please) molecular motion slows down, almost to a halt. However, at high temperatures, or even normal, every day temperatures, the intermolecular forces are very small and tend to be considered negligible. Introduction. While the Kinetic- Molecular Theory does an excellent job explaining gases, there are a few properties it does not explain regarding its description of real gases. The theory assumes that collisions between gas molecules and the walls of a container are perfectly elastic, gas particles do not have any volume, and there are no repulsive or attractive forces between molecules. These assumptions pertain to Ideal Gases. Gases tend to behave ideally in two different situations. First, they behave ideally at High Temperatures! Second, they behave ideally at Low Pressures! Gases behave non ideally at cold temperatures because of the fact that at cold temperatures, molecules are moving relatively slowly past one another, allowing for the repulsive and/or attractive forces between molecules to take effect, deviating from an Ideal Gas. Gases also behave non ideally at High Pressures, because at high pressures, the volume of molecules becomes a factor. Real gases and the molar volume. To illustrate the slight differences between the numerical properties of real and ideal gases at normal temperatures and pressures consider the following comparison. You will remember that we used the ideal gas equation to work out a value for the molar volume of an ideal gas at STP (standard temperature and pressure). If you know the density of a gas at a particular temperature and pressure, it is very easy to work out its molar volume. For example, at 2. K and 1 atmosphere pressure, the density of helium is 0. That means that 0. STP. It is a fairly simple sum to work out what 1 mole of helium, He, would occupy. The mass of 1 mole of He is 4 g and would occupy\. If you do this for a random sample of other gases, you get these values (to 3 significant figures) for the molar volume at STP (2. K and 1 atmosphere pressure). Table 1: Molar Volume and densities of select gases density (g dm- 3)molar volume at stp. He. 0. 1. 78. 52. N2. 1. 2. 50. 62. O2. 1. 4. 29. 02. CH4. 0. 7. 17. 22. CO2. 1. 9. 77. 22. C2. H4. 1. 2. 60. NH3. 0. 7. 69. 22. SO2. 2. 9. 26. 21. So although for simple calculation purposes we use the value 2. Even at ordinary temperatures and pressures, real gases can deviate slightly from the ideal value. The effect is much greater under more extreme conditions, as we will see next.
![]() Compression factors. For an ideal gas, \(p. V = n. RT\). If p. V and n. RT are the same, and you divide one by the other, then the answer will, of course, be 1. For real gases, \(p. V \neq n. RT\), and so the value will be something different. ![]() Another way to think of this is by taking a look at the compressibility factor: \. It can be expressed as the ratio \(PV/n. RT\) By analyzing this mathematically, we can clearly see that the compressibility factor is equal to 1 in an ideal gas, because\. The same is true for when a temperature decreases, as the compressibility factor rises above 1 again as the temperature approaches a smaller number. An ideal gas has a compressibility factor equal to one, but the compressibility factor for a real gas can vary greatly from this number. How and why real gases differ from ideal gases. I want to use this to illustrate the slight differences between the numerical properties of real and ideal gases at normal temperatures and. Derivation of van der Waals equation for real gases; Characteristics of van der Waals constants; Explanation of deviations using van der Waals equation; Merits & Applications; Critical constants; BEHAVIOUR OF. The Properties of Real Gases Book Title. To view the rest of this content please follow the download PDF link above. Gases: Properties and Behaviour Gas Laws Partial Pressures Kinetic Theory and Ideal Gases Real Gases Diffusion and Effusion. These particles move fast and independently of each other. Such properties allow. Kinetic Theory of Gases. Gases that deviate from ideality are known as Real Gases, which. To illustrate the slight differences between the numerical properties of real and ideal gases at normal. The graphs below show how this varies for nitrogen as you change the temperature and the pressure. Figure 1: Compressibility of nitrogen If nitrogen were an ideal gas under all conditions of temperature and pressure, every one of these curves would be a horizontal straight line showing a compression factor of 1. That's obviously not true! Things to notice. At low pressures of about 1 bar (1. Pa - just a bit less than 1 atmosphere), the compression factor is close to 1. Nitrogen approximates to ideal behavior at ordinary pressures. The non- ideal behavior gets worse at lower temperatures. For temperatures of 3. K, the compression factor is close to 1 over quite a large pressure range. The nitrogen becomes more ideal over a greater pressure range as the temperature rises. The non- ideal behavior gets worse at higher pressures. There must be at least two different effects causing these deviations. There must be at least one effect causing the p. V / n. RT ratio to be too low, especially at low temperatures. And there must be at least one effect causing it to get too high as pressure increases. We will explore those effects in a while. Other gases. Is the same behavior shown by other gases? The next diagram shows how the compression factors vary with pressure for a variety of gases at a fixed temperature. Figure 2: Compressibility of select gases. If you were to redo the set of original nitrogen graphs (at varying temperatures) for any of these other gases, you would find that each of them will produce a set of curves similar to the nitrogen ones. What varies is the temperature at which the different graph shapes occur. For example, if you look at the carbon dioxide graph at 2. K (Figure 2), it looks similar to the nitrogen one at 1. K from the first set of curves, although it does not increase so steeply at higher pressures. It is easy to say that gases become less ideal at low temperatures, but what counts as a low temperature varies from gas to gas. The closer you get to to the temperature at which the gas would turn into a liquid (or, in the case of carbon dioxide, a solid), the more non- ideal the gas becomes. What causes non- ideal behavior? In the compression factor expression, p. V / n. RT, everything on the bottom of the expression is either known or can be measured accurately. But that's not true of pressure and volume. In the assumptions we make about ideal gases, there are two statements which say things which can't be true of a real gas, and these have an effect on both pressure and volume. The volume problem. The kinetic theory assumes that, for an ideal gas, the volume taken up by the molecules themselves is entirely negligible compared with the volume of the container. For a real gas, that assumption isn't true. The molecules themselves do take up a proportion of the space in the container. The space in the container available for things to move around in is less than the measured volume of the container. Figure 3: This problem gets worse the more the gas is compressed. If the pressure is low, the volume taken up by the actual molecules is insignificant compared with the total volume of the container. But as the gas gets more compressed, the proportion of the total volume that the molecules themselves take up gets higher and higher. You could imagine compressing it so much that the molecules were actually all touching each other. At that point the volume available for them to move around in is zero! Suppose at some high pressure, you measure the volume of the container as, say, 1. The ideal gas equation was worked out by doing calculations based on Kinetic Theory assumptions. The V in p. V is assumed to be the volume which the molecules are free to move around in - but in this case, it would only be 9. If you worked out the compression factor, p. V / n. RT, by putting the total volume of the container into the formula, the answer is bound to be higher than it ought to be. It does not allow for the volume taken up by the molecules themselves. Let's just repeat one of the earlier diagrams so that you can see this effect in operation. Figure 4: For a real gas like nitrogen, notice how the compression factor tends to increase with pressure. For an ideal gas, the compression factor would be 1 over the whole pressure range. The value of the compression factor is too high at high pressures for a real gas. The reason for that is that the measured volume that you put into the expression is too high because you are not allowing for the volume taken up by the molecules. That error gets relatively worse the more compressed the gas becomes. The pressure problem. Another key assumption of the Kinetic Theory for ideal gases is that there are no intermolecular forces between the molecules. That is wrong for every real gas. If there weren't any intermolecular forces then it would be impossible to condense the gas as a liquid. Even helium, with the weakest of all intermolecular forces, can be turned to a liquid if the temperature is low enough. So what effect do intermolecular forces have? For a gas molecule in the middle of the gas, there is no net effect. It will be attracted to some extent to all the other molecules around it, but, on average, those attractions will cancel each other out. Attractions from behind a molecule, tending to slow it down, will be canceled out by attractions from in front of it, tending to speed it up. Figure 5. Despite all the intermolecular forces it is experiencing, the molecule picked out in green will just continue to move in the same direction at the same speed. That's different if the molecule is just about to hit the wall of the container. Now there are not any gas molecules in front of it, and the net pull is backwards into the body of the gas. The molecule will slow down just before it hits the wall. If it slows down, it will hit the wall less hard, and so exert less pressure. The overall effect of this is to make the measured pressure less than it would be if the gas was ideal. That means that if you put the measured pressure into the expression p. V / n. RT, the value of the compression factor will be less than it would be if the gas was ideal. This is why, under some conditions, graphs of compression factors drop below the ideal value of 1. ![]() Army Regulation 6. The Army Weight Control Program. Chapter 1 Introduction. Chapter 2 Responsibilities. Chapter 3 Proper Weight Control. References. Standard Methods for Determining Body Fat Using Body Circumferences, Height, and Weight. Nutrition Guide to the Weight Control Program. Table List. Figure List. Army Weight Control Program Glossary History. This publication is a rapid action revision. The portions affected by this rapid action revision are listed in the summary of change. 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Estado mundial de la infancia de 2. La adolescencia: una . A otro tipode entidades se les solicitar. RESTITUIR DERECHOS VIOLADOS EN EL TRABAJO INFANTIL. Adolescente costarricense env. Su ensayo es una de las seis voces adolescentes del mundo que aparecen en el estudio dedicado, en esta oportunidad, a: “La Adolescencia: una . Paolo hace un llamado para mejorar la calidad de la educaci. Adolescencia en Costa Rica El informe se. Indica que 6. 9 de cada 1. En Estados Unidos esa tasa fue de 4. ![]() Espa. Respecto a la educaci. Sin embargo, la tasa promedio de Costa Rica fue inferior a la registrada en Colombia (6. Brasil (7. 7). En el mundo Invirtiendo en los 1. Se calcula que uno de cada cinco adolescentes padece alg. En un mundo donde en 2. ![]() Estado Mundial de la infancia 2014.![]() ![]() Un mercado laboral cada vez m. Por ejemplo, asistiendo a congresos nacionales de la juventud y a foros juveniles, o tomando parte en iniciativas de servicio comunitario y de activismo en l. PNUD y UNICEF (Programa de las. Estado mundial de la infancia. Estado Mundial de la Infancia. 2011.La adolescencia: Una . El Estado Mundial de la Infancia de 2011 invit. Download Causas Y Efectos De La Adolescencia Iv estado mundial de la infancia 2011 estado mundial de la infancia 2011 contenido la adolescencia: una . ![]() |
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